Remarkable martensitic microstructures are observed in the alloy Ti76Nb22Al2, which undergoes a cubic to orthorhombic transformation with six martensitic variants Ui =UT i >0having middle eigenvalue 2(Ui) very close to 1. Assuming that 2(Ui) = 1 there are exactly 12 matrices in the set of energy wells 6 i=1 SO(3)Ui that are rank-one connected to 1. This set of 12 matrices has no rank-one connections. We attempt to understand the observed microstructures by studying gradient Young measures, exact gradients and TN-con gurations supported on these 12 matrices. This is joint work with Tomonari Inamura and Francesco Della Porta.